Unfortunately neither of those is correct, wrong number of words and the use of an & rather than "and" in the clue is deliberate since it's written that way in the titles, but I am happy to accept Captain Planet and the Planeteers as the fifth answer but not one of the clues I gave, with a meaningless bonus point for Captain Caveman and the Teenangels since I can't be arsed to look it up.
The other clues:
3: Captain Vorpatril's Alliance by Lois McMaster Bujold
4: The Void Captain's Tale by Norman Spinrad
7: The Captain's Table - a Star Trek novel and short story anthology series, various authors
8: Space Pirate Captain Harlock - Japanese animated series
9: The Return of Captain Invincible - Australian superhero movie, a musical
10: Captain Simian & The Space Monkeys - American animated series.
And that puts Cmdr James in the hot seat.... turning the power up to 11. Over to you!